Chlorido{1-[(dimethylamino)methyl]ferrocenyl-κ2 C 2,N}(tri­phenyl­stibine-κSb)palladium(II)

نویسندگان

  • Diego Pérez
  • Pankaj Sharma
  • Manju Sharma
  • Simón Hernández
چکیده

In the title compound, [FePdCl(C5H5)(C8H11N)(C18H15Sb)], obtained by reaction of diphen-yl(N,N-di-methyl-amino-methyl-ferrocen-yl)stibine with sodium tetra-chlorido-palladate(II) in acetone, the Pd(II) atom is coordinated in a slightly distorted square-planar geometry by a C atom of the ferrocenyl ring, and by N, Cl and Sb atoms. The Sb and N atoms are trans to each other.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Chlorido{2-[(dimethyl­amino)­methyl]phenyl-κ2 C 1,N}(1-methyl-1H-imidazole-κN 3)palladium(II)

In the title compound, [Pd(C(9)H(12)N)Cl(C(4)H(6)N(2))], which was synthesized from the reaction of 1-methyl-imidazole with dimeric dichloridobis[2-(dimethyl-amino)-benz-yl]palla-dium(II), the ring-deprotonated N,N-dimethyl-benzyl-amine ligand acts in a C,N-bidentate fashion. The dihedral angle between the ring of the 1-methyl-imidazole ligand and the palladacycle plane is 57.88 (16)°. The two ...

متن کامل

(SP-4-2)-Chlorido{N-[2-(diphenyl­phosphan­yl)benzyl­idene]benzyl­amine-κ2 P,N}(meth­yl)palladium(II)

In the title Pd(II) complex, [Pd(CH(3))Cl(C(26)H(22)NP)], the Pd(II) atom is coordinated in a slightly distorted square-planar geometry by the imino N and phosphane P atoms of the ligand, by one chloride ion and by a methyl ligand. The methyl group is trans to the N atom of the ligand.

متن کامل

Di-μ-chlorido-bis­{[μ-1,8-bis­(diisopropyl­phosphan­yl)-9,10-dihydro-9,10-ethano­anthracene-κ2 P:P′]-μ-chlorido-μ-methyl­idene-dipalladium(II)} tetra­hydro­furan penta­solvate

The title compound, [Pd(4)(CH(2))(2)Cl(4)(C(28)H(40)P(2))(2)]·5C(4)H(8)O, possesses a tetra-nuclear palladium core with four bridging chlorido ligands and two bridging methyl-ene units, as well as two bridging anthracene-based bis-phosphine ligands. This tetra-nuclear complex can be considered as being composed of two μ-chlorido-bridged LPd(2) units. The structural motif of these LPd(2) units s...

متن کامل

μ-Azido-κ2 N 1:N 1-μ-chlorido-bis­[(2-chloro-3-dimethyl­amino-1-phenyl­prop-1-en-1-yl-κ2 C 1,N)palladium(II)] chloro­form monosolvate

In the binuclear title complex, [Pd2(C11H13ClN)2Cl(N3)]·CHCl3, each Pd(II) atom has a slightly distorted square-planar geometry being coordinated by a C and an N atom of the 2-chloro-3-dimethyl-amino-1-phenyl-propyl ligand, a bridging Cl atom and an N atom of a bridging end-on azide group. There is a short intra-molecular C-H⋯Cl contact in the complex mol-ecule. In the crystal, the chloro-form ...

متن کامل

Chlorido[4-(pyridin-2-yl-κN)pyrimidine-2-sulfonato-κ2 N 3,O]palladium(II)

In the title compound, [Pd(C(9)H(6)N(3)O(3)S)Cl], the Pd(II) ion is coordinated by one O and two N atoms from a 4-(pyridin-2-yl)pyrimidine-2-sulfonate ligand and one chloride anion in a distorted square-planar geometry. In the crystal, all mol-ecules are situated on mirror planes and inter-act through weak inter-molecular C-H⋯O hydrogen bonds.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره 69  شماره 

صفحات  -

تاریخ انتشار 2013